PreservativePolyhydroxy acidIn every formula

Gluconolactone

Gluconolactone · INCI Gluconolactone

Every product with water in it has to be preserved. Gluconolactone is part of how ours is, working with sodium benzoate at the pH sodium citrate holds. It is also a polyhydroxy acid, and that has led to some confusion worth clearing up.

It is part of our preservative, with sodium benzoate. It is also a PHA, and at the level we use, its job in the bottle is preserving.

Gluconolactone, made by fermentation and part of the preservative in every formula.
Gluconolactone, made by fermentation and part of the preservative in every formula.

What it is

Gluconolactone is made by fermenting glucose. In water it slowly converts to gluconic acid. It is gentle, well tolerated, and accepted under the organic cosmetic standards, which is why we chose it.

Two things keep each bottle sound. The first is the preservative, a ready-made blend of sodium benzoate and gluconolactone. Sodium benzoate does the preserving, and gluconolactone helps it work. The second is the pH. Sodium citrate buffers the cream at pH 5 to 5.5, close to the skin's own. At the end of making, the pH is checked and fine-tuned with a little sodium hydroxide or citric acid.

Gluconolactone has several hydroxyl groups that hold water, so it acts as a light humectant as well as part of the preservative. It also binds trace metals in the cream, which helps keep the formula stable. At much higher strengths it is studied as a gentle exfoliant; at the level we use, it does not exfoliate.

What it does in our formulas

Gluconolactone is part of the preservative in every formula. It also holds a little water and binds trace metals.

01

It helps preserve the product

Sodium benzoate does the preserving, and gluconolactone helps it work. In water, gluconolactone slowly converts to gluconic acid. Sodium citrate buffers the cream at pH 5 to 5.5, where the pair works. Any product containing water needs preserving, ours included.

Well characterised
02

It holds water

Gluconolactone has several hydroxyl groups that hold water, so it acts as a light humectant as well as part of the preservative.

Well characterised
03

It binds trace metals

Gluconolactone binds trace metals in the cream, which helps keep the formula stable.

Well characterised

What the research does not show

Two claims made around gluconolactone need correcting.

Marketed as A PHA that resurfaces and exfoliates your skin
Gluconolactone is a polyhydroxy acid, and at the levels used in exfoliating products, several times what is in ours, PHAs do gently smooth the skin. We use it at just over one percent, as part of the preservative. At that level it is not exfoliating your skin.
Marketed as Preservative-free, or self-preserving
Anything containing water will grow bacteria and mould without a preservative. Ours is sodium benzoate working with gluconolactone, and both are on the label.

On the label and in the range

Gluconolactone appears in every one of our formulations, in the middle of the ingredient list, with sodium benzoate further down. The two make up the preservative, so read them as a pair. The exact percentage is published on each product page.

Is it suitable for me?

Gluconolactone is well tolerated on sensitive skin. It suits a vegan routine, is accepted under the organic cosmetic standards, and carries no restrictions under UK or EU cosmetic law.

Vegan-friendlySensitive-skin suitableWell tolerated

As with anything new, if your skin reacts easily it is worth patch testing first.

Every formulation published
Every formulation published
Science led
Science led
Made to be gentle on skin
Made to be gentle on skin

The research behind this page

We review the published literature. We do not conduct the studies below.

  1. Grimes PE, Green BA, Wildnauer RH, Edison BL. The use of polyhydroxy acids (PHAs) in photoaged skin. Cutis 2004;73(2 Suppl):3-13. →
  2. Green BA, Yu RJ, Van Scott EJ. Clinical and cosmeceutical uses of hydroxyacids. Clin Dermatol 2009;27(5):495-501. →
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